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木下　英典 キノシタ ヒデノリ

■所属部署名 理工学研究科　物質科学部門 ■電話番号
■職名 准教授 ■FAX番号
■住所 埼玉県さいたま市桜区下大久保255 ■メールアドレス hkino＠mail.saitama-u.ac.jp
■ホームページURL

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兼担研究科・学部

工学部 応用化学科

研究分野

有機化学
合成化学
キーワード：有機化学 , 合成化学 , 有機金属化学 , 遷移金属化学

所属学会

所属学会
有機合成化学協会
日本化学会
近畿化学協会
アメリカ化学会

学歴

出身大学院・研究科等
2005 , 京都大学大学院 , 博士 , 工学研究科 , 材料化学専攻 , 修了
2002 , 京都大学大学院 , 修士 , 工学研究科 , 材料化学専攻 , 修了
出身学校・専攻等(大学院を除く)
2000 , 京都大学 , 工学部 , 工業化学科
取得学位
博士（工学） , 京都大学

研究職歴等

研究職歴
2017 , 埼玉大学大学院理工学研究科 准教授
2009 - 2017 , 埼玉大学大学院理工学研究科　助教
2007 - 2009 , 米国ボストン大学　博士研究員
2005 - 2007 , ファイザー（株）中央研究所　研究員
2002 - 2005 , 日本学術振興会　特別研究員 DC1

研究活動業績

研究業績(著書・発表論文等)

論文
Synthetic Route to Benzostannoles via Al-Li-dimetal Intermediate and Their Application to Dibenzofulvene Synthesis
Advanced Synthesis & Catalysis,366(7):1523-1530 2024
Rei Kurokawa, Hidenori Kinoshita,* and Katsukiyo Miura

Palladium-Catalyzed Synthesis of 3,6-Diaryl-1-silylfulvenes: A Promising Entry for Preparing 1,3,6-Triarylfulvenes Bearing Three Different Aryl Groups
Organic Letters,25(8):1331–1335. 2023
Hayato Ohki, Hidenori Kinoshita,* Katsukiyo Miura

One-pot Direct Synthesis of Siloles from 1-Bromo-2-silylethynylbenzenes or 1-Bromo-4-silyl-1,3-enynes
The Journal of Organic Chemistry,87(15):10416–10421. 2022
Koyo Kazama, Rei Kurokawa, Kei Inoue, Hidenori Kinoshita,* and Katsukiyo Miura

Electrochemical Properties and Electrochromism of 6-Aryl-1,3-bis(trimethylsilyl)fulvenes and Their Derivatives
The Journal of Organic Chemistry,87(1):172–183. 2022
Ryota Tatemura, Mikio Yasutake, Hidenori Kinoshita*, and Katsukiyo Miura

Regio- and stereoselective synthesis of bromoalkenes by homolytic hydrobromination of alkynes with hydrogen bromide
Tetrahedron,78:132687 2022
Wataru Kumaki, Hidenori Kinoshita, and Katsukiyo Miura*

Cyclization of 1-ethynyl-2-alkenylbenzenes to naphthalenes using Et2AlCl and DIBAL-H
Tetrahedron Lett.,62:TETL_152682 2021
Yuma Nonoyama, Kazuki Yaguchi, Hidenori Kinoshita,* and Katsukiyo Miura

Synthesis of Polysubstituted Germoles and Benzogermoles Using a Substoichiometric Amount of Diisobutylaluminum Hydride
Organic Letters　,23(12):4598-4602. 2021
Ko Kojima, Seiya Uchida, Hidenori Kinoshita,* and Katsukiyo Miura

Diisobutylaluminum Hydride Promoted Selectivity-Switchable Synthesis of Benzothiophene Oxides and Benzothiophenes via an Al-Li-dimetallated Intermediate
Organic Letters,22(8):3123-3127 2020
Seiya Uchida, Hidenori Kinoshita,* and Katsukiyo Miura*

Palladium-Catalyzed Synthesis of 1,3-Bissilyl-6-arylfulvenes via Cyclotrimerization of Trimethylsilylacetylene and Desilylation
Organic Letters,21(6):1612-1616. 2019
Souta Suzuki, Hidenori Kinoshita,* and Katsukiyo Miura*

水素化ジイソブチルアルミニウムによる分子内炭素-炭素および炭素-ケイ素結合形成反応の開発　Development of Intramolecular C-C and C-Si Bond Forming Reactions Promoted by Diisobutylaluminum Hydride
「有機合成化学協会誌」 総合論文 JOURNALl of Synthetic Organic Chemistry JAPAN,77(1):58-68 2019
木下英典、三浦勝清 (Hidenori Kinoshita,* Katsukiyo Miura*)

Indium(III)-catalyzed intramolecular addition of silyl enolates to alkynes
Tetrahedron Letters,60(26):1732-1735 2019
Hidenori Kinoshita, Kenta Negishi, Saya Fushimi, and Katsukiyo Miura

Syntheses of Substituted Benzosiloles and Siloles by Diisobutylaluminium Hydride-promoted Cyclization of 1-Silyl-2-(2-silylethynyl)benzenes and 1,4-Disilylalk-3-en-1-ynes
Tetrahedron,74(14):1632-1645 2018
Hidenori Kinoshita,* Hiroki Fukumoto, Akihiro Ueda, and Katsukiyo Miura

Diisobutylaluminum Hydride-promoted Cyclization of 1-Hydrosilyl-4-silyl-1,3-enynes to Polysubstituted Siloles
Organic Letters,19(4): 882-885 2017
Hidenori Kinoshita, Akihiro Ueda, Hiroki Fukumoto, and Katsukiyo Miura

Diisobutylaluminum hydride-promoted cyclization of silylated 1,3-dien-5-ynes: Application to total synthesis of a 20-norabietane derivative
Tetrahedron Letters,58(16):1607-1610 2017
Hidenori Kinoshita, Kazuki Yaguchi, Takayuki Tohjima, and Katsukiyo Miura

Cyclization of alk-5-ynyl ketones promoted by Tf2NH and In(OTf)3: selective synthesis of 5- and 7-membered carbocycles
Tetrahedron Letters,57:5065-5069 2016
Hidenori Kinoshita, Chika Miyama, and Katsukiyo Miura

Diisobutylaluminum Hydride-Promoted Cyclization of o-(Trimethylsilylethynyl)styrenes to Substituted Naphthalenes
Tetrahedron Letters,57(19):2039-2043 2016
Hidenori Kinoshita, Kazuki Yaguchi, Takayuki Tohjima, Nobuyoshi Hirai, Katsukiyo Miura

Regioselective Allylation of Carbon Electrophiles with Alkenylsilanes under Dual Catalysis by Cationic Platinum(II) Species
Synthesis,48:520-534 2016
Hidenori Kinoshita, Ryosuke Kizu, Masahiro Horikoshi, Gen Inoue, Masayuki Fujimoto, Masanori Saito, Junji Ichikawa, Akira Hosomi, and Katsukiyo Miura

Diisobutylaluminum hydride-promoted cyclization of benzyl and phenylsilyl ethers bearing a 2-(trimethylsilyl)ethynyl group: syntheses of indenes and benzosiloles
Tetrahedron Letters,57(31):3571-3574 2016
Hidenori Kinoshita, Hiroki Fukumoto, Takayuki Tohjima, and Katsukiyo Miura

Platinum-Catalyzed Allylation of Carbon Electrophiles with Alkenylsilanes
Tetrahedron Letters,56:713-716 2015
Hidenori Kinoshita, Ryosuke Kizu, Gen Inoue, Masayuli Fujimoto, Masanori Saito, Junji Ichikawa, Akira Hosomi, and Katsukiyo Miura

Diisobutylaluminum Hydride-Promoted Cyclization of o-(Trimethylsilylethynyl)styrenes to Indenes
J. Org. Chem.,79:8171-8181 2014
Hidenori Kinoshita, Nobuyoshi Hirai, and Katsukiyo Miura

Hydroalumination-Triggered Cyclization of Silylated 1,3-dien-5-ynes to Polysubstitiuted Benzenes
Org. Lett.,16:4762-4765 2014
Hidenori Kinoshita, Takayuki Tohjima, and Katsukiyo Miura

Regioselective Synthesis of Multisubstituted Benzenes by Palladium-Catalyzed Intermolecular Reaction of β-Iodo-β-silylstyrenes with Alkynes
Organic Letters,15: 2962-2965 2013
Hidenori Kinoshita, Hirotoshi Takahashi, and Katsukiyo Miura

Nucleophilic Addition of α-(Dimethylsilyl)nitriles to Aldehydes and Ketones
Organic Letters,15:3750-3753 2013
Takaaki Jinzaki, Mitsuru, Arakawa, Hidenori Kinoshita, Junji Ichikawa, and Katsukiyo Miura

Platinum-Catalyzed One-Pot Alkenylation of Aldehydes Using Alkynes and Triethylsilane: Dual Catalysis by Platinum(II) Chloride
Organic Letters,15:5538–5541 2013
Hidenori Kinoshita, Ryousuke Uemura, Daiki Fukuda, and Katsukiyo Miura

Synthetic Utility of Tribenzyltin Hydride and Its Derivatives as Easily Accessible, Removable Organotin Reagents
J. Organomet. Chem.,724:129-134 2013
Takeshi Yamakawa, Hidenori Kinoshita, and Katsukiyo Miura

Dialkylaluminum Hydride-Promoted Cyclodimerization of Silylated 1,3-Enynes via Skeletal Rearrangement
American Chemical Society,Organic Letters,13:6192 2011
Hidenori Kinoshita, Tomoyuki Ishikawa, and Katsukiyo Miura
電子ジャーナル Web Of Science

Indium(III)-catalyzed Coupling between Alkynes and Aldehydes to a,b-Unsaturated Ketones
Chemical Society of Japan,Chemistry Letters,39(7):766-767 2010
Katsukiyo Miura, Kiyomi Yamamoto, Aya Yamanobe, Keisuke Ito, Hidenori Kinoshita, Junji Ichikawa, and Akira Hosomi

Tandem Processes Identified from Reaction Screening: Nucleophilic Addition to Aryl N-Phosphinylimines Employing La(III)-TFAA Activation
American Chemical Society,Journal of the American Chemical Society,132(12):6412–6418 2010
Hidenori Kinoshita, Oscar J.Ingham, Winnie W.Ong, Aaron B.Beeler and John A.Porco, Jr.
電子ジャーナル

Platinum-Catalyzed Nucleophilic Addition of Vinylsilanes at the β-Position
American Chemical Society,Organic Letters,11(21):5066-5069 2009
Katsukiyo Miura, Gen Inoue, Hisashi Sasagawa, Hidenori Kinoshita, Junji Ichikawa and Akira Hosomi

Pltinum(II)-catalyzed Acetal-Ene Reaction: Easy Access to Homoallylic Ethers
Chemical Society of Japan,Chemistry Letters,38(12):1204-1205 2009
Katsukiyo Miura, Hiroyuki Izumi, Hidenori Kinoshita, Junji Ichikawa, and Akira Hosomi

Synthesis of Medium- and Large-Sized Lactones in an Aqueous-Organic Biphasic System
Wiley InterScience,Angew. Chem. Int. Ed.,44(16):2397-2400 2005
Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
電子ジャーナル Web Of Science

1,2-Migration of Phosphorus-Centered Anions on Ate-type Copper Carbenoids and Its Application for the Synthesis of New Potent Phosphine Ligands
American Chemical Society,Organic Letters,7:5713-5715 2005
Junichi Kondo, Hidenori Someya; Hidenori Kinoshita, Hiroshi Shinokubo, Hideki Yorimitsu, Koichiro Oshima

Water Enables Direct Use of Allyl Alcohol for Tsuji-Trost Reaction without Activators
American Chemical Society,Org. Lett.,6(22):4085-4088 200410
Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
電子ジャーナル Web Of Science

Hydrosilylation of Alkynes with Cationic Rhodium Species Formed in Anionic Micellar System
American Chemical Society,Org. Lett.,6(13):2217-2220 200406
Akinori Sato, Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
電子ジャーナル Web Of Science

Phosphane-Free Rhodium Catalyst in an Aqueous Micellar System for [4+2] Annulation of Dienynes
Wiley InterScience,Angew. Chem. Int. Ed.,43(14):1860-1862 2004
Dai Motoda, Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
電子ジャーナル Web Of Science

Rhodium-Catalyzed [2+2+2] Cyclotrimerization in an Aqueous-Organic Biphasic System
American Chemical Society,J. Am. Chem. Soc.,125(26):7784-7785 200307
Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
電子ジャーナル Web Of Science

Preparation of Allylic Germanes with Tri(2-furyl)germane via π-Allylpalladium Species
Thieme Chemistry,Synlett(11):1916-1918 200211
Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
Web Of Science

A Room Temperature Kharasch Reaction Catalyzed by Pd(0) in a Heterogeneous Aqueous System
Wiley InterScience,Adv. Synth. Catal.,344(3-4):261-265 200205
Dai Motoda, Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
Web Of Science

Pd(0)-Catalyzed Reaction of Alkynes with Trifurylgermane and CO Providing Acylgermanes: The Example of Hydrometalcarbonylation of Alkyne
American Chemical Society,J. Am. Chem. Soc.,124(16):4220-4221 200204
Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima
Web Of Science

Biaryl Synthesis from Two Different Aryl Halides with Tri(2-furyl)germane
American Chemical Society,Organic Letters,4:3165-3167 2002
Tomoaki Nakamura, Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

Remarkable Rate Acceleration of Pd(0)-Catalyzed Hydrogermylation of Alkynes and Dienes in Water
American Chemical Society,Org. Lett.,3(16):2521-2524 200108
Hidenori Kinoshita, Tomoaki Nakamura, Hirotada Kakiya, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima
Web Of Science

Trialkylmanganate Mediated Radical Addition of Triphenylgermane to Carbon-Carbon Multiple Bonds
The Chemical Society of Japan,Bull. Chem. Soc. Jpn.,73(9):2159-2160 200009
Hidenori Kinoshita, Hirotada Kakiya and Koichiro Oshima
Web Of Science

研究費

科学研究費補助金(研究代表者)
2023-2025 , 異なる置換基を有する多置換スタンノールの合成とエレクトロクロミック材料への変換 , 基盤研究(C)（一般）
2020-2022 , 異なる置換基を有する多置換フルベンの合成とエレクトロクロミズム材料への応用 , 基盤研究(C) （一般）
2012-2013 , アルミニウム反応剤と有機ケイ素化合物を利用した位置選択的多置換ベンゼン合成と応用ルミニウム反応剤と有機ケイ素化合物を利用した位置選択的多置換ベンゼン合成と応用 , 若手研究(B)
2009-2009 , 水の特異性を利用した効率的有機合成法の確立 , 研究活動スタート支援